Right, and this sweet little chip already has the PWM output and the analog comparator, and you can get a wakeup interrupt from the comparator. And then there's the VFC/VCO approach someone else suggested. But I think you can get a higher sample rate with a dedicated ADC. How fast can you do the PWM/comparator trick on a device like this?
You can always get a higher rate with a dedicated chip, and they are pretty cheap these days. The max you can do the pwm trick is a function of the max clock rate, divide down pwm clock, and the number of bits you want for resolution. Take a look here:
