I can't tell whether you're trolling or serious...
It's not about moderators being harmed or not. It's a preference of the wider community to not have the harmful content, and the moderators volunteering to help keep it that way.
With most harmful content, the effect of seeing a single instance is not significant. Being exposed to it constantly in places you frequent for other reason (your online communities, or advertisements everwhere), builds up much more of an effect. Now moderators being constantly exposed might also be affected, but they're choosing to do so, and may have coping strategies in place for the more extreme cases.
What's the deal with trying so hard to defend the advertising of an objectively harmful industry?
I think a good parallel here is Tobacco advertising. Smoking is harmful in every way, therefore I don't see any reason why advertising it to a broad audience (which will inadvertently also include children) is something we should allow.
What's the net benefit of allowing such advertising? I don't see it. Yo could argue something about rights to free speech or some variation, but societies still have a responsibility to look out for the health of their people, no?
Yeah that's true, random unrelated things did happen in the past, but that's not a credible argument against having slap on the wrist fines for advertising gambling.