If you lick just one, you feel nothing. You have to lick both.
However if you set things up so that one terminal of a 9v battery is grounded, and you lick the other terminal (just one), you would feel something.
(You would also have to be grounded, at 9v that would probably require barefoot on slightly wet ground. At 120v it's a lot easier to be grounded, but the principle is the same - you only feel the electricity because the ground itself provides a return path.)
However if you set things up so that one terminal of a 9v battery is grounded, and you lick the other terminal (just one), you would feel something.
(You would also have to be grounded, at 9v that would probably require barefoot on slightly wet ground. At 120v it's a lot easier to be grounded, but the principle is the same - you only feel the electricity because the ground itself provides a return path.)