If you can measure the front and back horizon accurately you can measure the left and right horizons too, and that will give you an accurate down vector.
But I don't think it's possible to measure a horizon that accurately. There are temperature and pressure dependent atmospheric effects at low angles that effect how light refracts and curves through the atmosphere, and these effects will have to be compensated for to measure the angle accurately. Additionally, there are mountains and valleys to compensate for.