There are many chemistries for batteries. We're even seeing some of them pushed to commercialization. Chemistries based on common elements like sodium or iron would evade concerns about material availability.
There are thermal storage technologies. An example is pumped thermal storage. This involves (1) adiabatically compressing argon, (2) transferring heat from the compressed argon to a hot store (say, molten "solar salt", a potassium/sodium nitrate salt mix) by a countercurrent heat exchanger, (3) expanding the cooled argon back to the initial pressure, (4) using that now cold argon to extract heat from a "cold store", say liquid hexane, cooling it to -100 C. To discharge, reverse this process. Round trip efficiencies similar to pumped hydro could be achieved. The high temperature side of this process is within the creep range of ordinary steel, so no exotic materials are required.
Resistively heated thermal stores would not be quite as efficient (maybe in the low 50s%) and involve higher temperature (~1200 C), but could work with existing gas turbines. Babcock and Wilcox are commercializing this now, using their very nifty direct contact sand/gas fluidized bed heat exchanger. The storage medium here would be ordinary sand, of which there is an unlimited supply.
This last approach also allows an external heat source, such as hydrogen combustion, to act as a backup heat source. So if your thermal stores run out, you can keep running them by burning hydrogen (or some other e-fuel). The marginal capital cost of this capability would be very low, just that of adding a fluidized bed hydrogen combustor to heat the sand.
Thermal storage has only been used for district heating. There is no commercial electric thermal storage project in existence. Babcock and Wilcox have not broken ground on a prototype thermal electric storage plant, let alone a commercial one. They signed an intellectual property agreement [1], this is not even remotely the same thing as commercialization.
Hydrogen electric storage has issues producing hydrogen without emitting fossil fuels: almost all hydrogen produced today is through steam reformation which emits carbon dioxide. Electrolysis has issues with corroding electrodes, in particular. We've known about electrolysis for decades (centuries?) but its disadvantages have not been solved. Likewise, how long have sodium and iron batteries been on the verge of commercialization? How long did lithium ion batteries take to reach the scale sufficient for EVs? Sources say that they're projection sodium ion batteries to be produced at 20 GWh per year by 2030 [2]. Even if that level of optimism pans out, this is nowhere near a scale sufficient for grid storage.
People still hope for lithium ion batteries to deliver, because it's the best (or least-bad) option and none of the competitors are set to unseat it. And remember, almost all of this battery production is going to EVs and electronics, only a fraction of it is going to grid storage.
There are thermal storage technologies. An example is pumped thermal storage. This involves (1) adiabatically compressing argon, (2) transferring heat from the compressed argon to a hot store (say, molten "solar salt", a potassium/sodium nitrate salt mix) by a countercurrent heat exchanger, (3) expanding the cooled argon back to the initial pressure, (4) using that now cold argon to extract heat from a "cold store", say liquid hexane, cooling it to -100 C. To discharge, reverse this process. Round trip efficiencies similar to pumped hydro could be achieved. The high temperature side of this process is within the creep range of ordinary steel, so no exotic materials are required.
Resistively heated thermal stores would not be quite as efficient (maybe in the low 50s%) and involve higher temperature (~1200 C), but could work with existing gas turbines. Babcock and Wilcox are commercializing this now, using their very nifty direct contact sand/gas fluidized bed heat exchanger. The storage medium here would be ordinary sand, of which there is an unlimited supply.
This last approach also allows an external heat source, such as hydrogen combustion, to act as a backup heat source. So if your thermal stores run out, you can keep running them by burning hydrogen (or some other e-fuel). The marginal capital cost of this capability would be very low, just that of adding a fluidized bed hydrogen combustor to heat the sand.