"75,000 years ago: Toba Volcano supereruption that may have contributed to human populations being lowered to about 15,000 people."
The key question is: How much CO2 did that super-eruption emit into the atmosphere?
In our hurry to attribute climate change to our meager impact on this planet, we tend to forget what horrors an eruption of this magnitude can cause. And who knows how many of them happened during the past millennia.
Water vapour is consistently the most abundant volcanic gas, normally comprising more than 60% of total emissions. Carbon dioxide typically accounts for 10 to 40% of emissions.
Citing: H. Sigurdsson et al. (2000) Encyclopedia of Volcanoes, San Diego, Academic Press.
(Late edit: though I note that this seems to discuss percentages of gaseous emissions, not total ejecta. Anyone have a better source here?)
One of the largest volcanic events I'm aware of is the Siberian Traps eruption, about 250 mya, with a volume of about 4 million km^3, another three orders of magnitude greater than Tomba.
This has been linked to the Permian–Triassic mass extinction event, with the mechanism being release of methane clathrates and/or stimulating growth of a microbe which released vast quantities of methane into the atmosphere, killing ~81% of all extant marine species and 70% of terrestrial vertebrate species.
"The level of atmospheric carbon dioxide rose from around 400 ppm to 2,500 ppm with approximately 3,900 to 12,000 gigatonnes of carbon being added to the ocean-atmosphere system during this period."
-- Wikipedia, citing Wu, Yuyang; Chu, Daoliang; Tong, Jinnan; Song, Haijun; Dal Corso, Jacopo; Wignall, Paul B.; Song, Huyue; Du, Yong; Cui, Ying (9 April 2021). "Six-fold increase of atmospheric pCO2 during the Permian–Triassic mass extinction". Nature Communications. 12 (1): 2137. Bibcode:2021NatCo..12.2137W. doi:10.1038/s41467-021-22298-7.
Yeah, it's the comparison between DRE and Gas ejecta that got me bogged down before.
Having now given up, I asked ChatG4. It says "the mass ratio between DRE and gaseous emissions might be on the order of 20:1 to 100:1", no citations ofc.
So, just as a strawman and using your 10-40%, on the low end .01.1 = 0.001, high end .05.4 = 0.02. So .1%-2% of ejecta by mass is CO2 emissions. Hah :)
Using my orig figure for Toba of a billion gigatons of ejecta, of which roughly a million gigatons would be CO2. Correct math?
> And who knows how many of them happened during the past millennia.
We at least have a significantly large list of what we know [1] - that's part of the purpose of core drilling, the ash deposits worldwide can be linked together to estimate where ash traveled to. Also, craters and their surrounding can be drilled into to determine eruption events.
Not even close to what we as humans emit. The rate of the global annual natural CO2 emissions are 1-2 orders of magnitude slower than anthropogenic emissions.
Considering the rapid rise in temperature on a relatively miniscule geological timescale, I'd be more interested to see evidence that it's not a manmade phenomenon.
The key question is: How much CO2 did that super-eruption emit into the atmosphere?
In our hurry to attribute climate change to our meager impact on this planet, we tend to forget what horrors an eruption of this magnitude can cause. And who knows how many of them happened during the past millennia.