We tried to do that with http://sopablackout.org. Granted, this drop shadow implementation will get people's attention more, but we wanted to focus on allowing people to learn why the site is blocked.
So I don't have to change the sites manually I check the date. Here is a snippet of php code to check the date and only include your .js on Jan 18, 2012:
I made an overlay version of the spotlight effect that still allows the site to function, if you like the effect but don't like the total blackout: https://github.com/nitrogenlogic/stop-sopa (there's also a nice dark version available in the dark branch).