Nicotine is more addictive than caffeine. I'm not going to find peer-reviewed, double-blind studies to back up my claim. I'm going to go with the anecdotes I've heard for decades and from personal experience.
There are "whole tobacco alkaloid" liquids (full-spectrum extract of tobacco vs. pure nicotine) available which contains a lot of the other stuff. Probably more addictive so I'd avoid it if your goal is to quit.