Steam turbines have row after row of blades, each successive blade wheel larger and lower pressure than the last. Exit temperatures from modern turbogenerators are around 120° C, where the steam is about to turn into water, and pressure is usually below atmospheric. Almost all the energy which thermodynamics permits to be extracted has been extracted.
I probably should have phrased it better - I was picturing [Furnace] | [Thermophotovoltaics] | [Boiler], so the PV part gets first crack at the light/IR from the furnace and then the boiler cools the PV gear as it boils the water. This is also how it's suggested to be used in a paper linked elsewhere in the discussion above: https://www.sciencedirect.com/science/article/pii/S030626191...